Di-μ-azido-κ4 N:N-bis({2-[(3-amino-2,2-dimethylpropyl)iminomethyl]-6-methoxyphenolato-1κ3 N,N′,O 1}copper(II))
نویسندگان
چکیده
The complete mol-ecule of the title complex, [Cu(2)(C(13)H(19)N(2)O(2))(2)(N(3))(2)], is generated by the application of a centre of inversion. The central Cu(2)N(2) core is a rhombus as the μ(2)-azide ligands bridge in an asymmetric fashion. Each Cu(II) atom is also coordinated by a monoanionic tridentate Schiff base ligand via the anti-cipated oxide O, imine N and amine N atoms. The resulting N(4)O coordination geometry is based on a square pyramid. No specific inter-molecular inter-actions are noted in the crystal packing, but the amine H atoms form intra-molecular N-H⋯O(oxide)/N(azide) hydrogen bonds.
منابع مشابه
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012